Chemistry of Thioamides

Nonfiction, Science & Nature, Science, Chemistry, Technical & Industrial, Organic
Cover of the book Chemistry of Thioamides by , Springer Singapore
View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart
Author: ISBN: 9789811378287
Publisher: Springer Singapore Publication: May 14, 2019
Imprint: Springer Language: English
Author:
ISBN: 9789811378287
Publisher: Springer Singapore
Publication: May 14, 2019
Imprint: Springer
Language: English

This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon–sulfur and carbon–carbon bonds, to asymmetric reactions, to formation of heterocycles are described.

Among the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features.

Thioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologically relevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book. 

View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart

This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon–sulfur and carbon–carbon bonds, to asymmetric reactions, to formation of heterocycles are described.

Among the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features.

Thioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologically relevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book. 

More books from Springer Singapore

Cover of the book Plasma Surface Metallurgy by
Cover of the book Pulse Current Gas Metal Arc Welding by
Cover of the book Advanced Business Analytics by
Cover of the book Proceedings of 2017 Chinese Intelligent Automation Conference by
Cover of the book Sound in the Time Domain by
Cover of the book Summer Report of China Industrial Economic Situation Analysis (2016) by
Cover of the book Industry-Led Growth by
Cover of the book Silviculture of South Asian Priority Bamboos by
Cover of the book Contemporary Chinese Rural Reform by
Cover of the book Computer Communication, Networking and Internet Security by
Cover of the book On To Mars! by
Cover of the book Empowering Social Workers by
Cover of the book Energy Conservation for IoT Devices by
Cover of the book Content-Based Image Retrieval by
Cover of the book University Social Responsibility and Quality of Life by
We use our own "cookies" and third party cookies to improve services and to see statistical information. By using this website, you agree to our Privacy Policy