Electrophosphorescent Polymers Based on Polyarylether Hosts

Nonfiction, Science & Nature, Technology, Textiles & Polymers, Material Science, Science
Cover of the book Electrophosphorescent Polymers Based on Polyarylether Hosts by Shiyang Shao, Springer Berlin Heidelberg
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Author: Shiyang Shao ISBN: 9783662443767
Publisher: Springer Berlin Heidelberg Publication: October 8, 2014
Imprint: Springer Language: English
Author: Shiyang Shao
ISBN: 9783662443767
Publisher: Springer Berlin Heidelberg
Publication: October 8, 2014
Imprint: Springer
Language: English

This thesis introduces a series of novel, non-conjugated polyarylether hosts that are not subject to the triplet-energy limitations of traditional conjugated polymer hosts. As a result of this major breakthrough, the long-standing problem of triplet energy back transfer has now been overcome, making it possible to design high-efficiency electrophosphorescent polymers (PhPs), especially the blue and all-phosphorescent white ones. In addition, the author proposes a spiro-linked hyperbranched architecture for PhPs to inhibit the undesired triplet energy back transfer process in low triplet-energy hosts. The work in this thesis provides vital new insights into the design of PhPs and has led to several publications in high-profile journals.

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This thesis introduces a series of novel, non-conjugated polyarylether hosts that are not subject to the triplet-energy limitations of traditional conjugated polymer hosts. As a result of this major breakthrough, the long-standing problem of triplet energy back transfer has now been overcome, making it possible to design high-efficiency electrophosphorescent polymers (PhPs), especially the blue and all-phosphorescent white ones. In addition, the author proposes a spiro-linked hyperbranched architecture for PhPs to inhibit the undesired triplet energy back transfer process in low triplet-energy hosts. The work in this thesis provides vital new insights into the design of PhPs and has led to several publications in high-profile journals.

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