Material Designs and New Physical Properties in MX- and MMX-Chain Compounds

Nonfiction, Science & Nature, Science, Chemistry, Organic, Technology, Material Science
Cover of the book Material Designs and New Physical Properties in MX- and MMX-Chain Compounds by , Springer Vienna
View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart
Author: ISBN: 9783709113172
Publisher: Springer Vienna Publication: December 13, 2012
Imprint: Springer Language: English
Author:
ISBN: 9783709113172
Publisher: Springer Vienna
Publication: December 13, 2012
Imprint: Springer
Language: English

This is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have one-dimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MX-chain complexes, the Pt and Pd units are in M(II)-M(IV) mixed valence or charge density wave (CDW) states due to electron-phonon interactions, and Ni compounds are in Ni(III) averaged valence or Mott-Hubbard states due to the on-site Coulomb repulsion. More recently, Pd(III) Mott-Hubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photo-induced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photo-induced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous third-order optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended Peierls-Hubbard model. For MMX-chain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photo-irradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically.

View on Amazon View on AbeBooks View on Kobo View on B.Depository View on eBay View on Walmart

This is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have one-dimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MX-chain complexes, the Pt and Pd units are in M(II)-M(IV) mixed valence or charge density wave (CDW) states due to electron-phonon interactions, and Ni compounds are in Ni(III) averaged valence or Mott-Hubbard states due to the on-site Coulomb repulsion. More recently, Pd(III) Mott-Hubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photo-induced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photo-induced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous third-order optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended Peierls-Hubbard model. For MMX-chain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photo-irradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically.

More books from Springer Vienna

Cover of the book Extracerebral Collections by
Cover of the book Herpes Simplex and Pseudorabies Viruses by
Cover of the book New Aspects for Treatment with Fosfomycin by
Cover of the book Yearbook on Space Policy 2010/2011 by
Cover of the book Cécile and Oskar Vogt: The Visionaries of Modern Neuroscience by
Cover of the book Store-operated Ca2+ entry (SOCE) pathways by
Cover of the book Hearing: Its Function and Dysfunction by
Cover of the book The Intervertebral Disc by
Cover of the book Psychiatry, Psychoimmunology, and Viruses by
Cover of the book The Foundations of Ethology by
Cover of the book Space,Time and Memory in the Hippocampal Formation by
Cover of the book Advances in Stereotactic and Functional Neurosurgery 10 by
Cover of the book Advances and Technical Standards in Neurosurgery by
Cover of the book Computer Animation and Simulation 2000 by
Cover of the book Computer Algebra in Quantum Field Theory by
We use our own "cookies" and third party cookies to improve services and to see statistical information. By using this website, you agree to our Privacy Policy