Viscometric Flows of Non-Newtonian Fluids

Theory and Experiment

We here attempt to give a complete but concise treatment of the theory of steady viscometric flows of simple (non-Newtonian) fluids and to use that theory to discuss the design and interpretation of ex­ periments. We are able to present the theory with less mathematical machinery than was used in our original papers, partly because this Tract has more limited aims than those papers, and partly because we employ a method, found by Noll and published here for the first time, for dealing with visco metric flows without the apparatus of rela­ tive Cauchy-Green tensors and reduced constitutive equations. To make the theory accessible to students not familiar with modern mathematics, we have added to our Tract an appendix explaining some of the mathe­ matical concepts essential to continuum physics. Pittsburgh, July 1965 BERNARD D. COLEMAN HERSHEL MARKOVITZ WALTER NOLL CONTENTS I. Introduction page 1. Limitations of the Classical Theory of Navier and Stokes. 1 5 2. Incompressible Simple Fluids. . . . . . . . . . . . 3. Plan and Scope of this Monograph . . . . . . . . . 7 II. Theory of Incompressible Simple Fluids 4. Kinematics. . . . . . . . . . . . 10 5. The Dynamical Equations . . . . . . . . . . . 12 6. The Principle of Material Objectivity . . . . . . 14 7. The Definition of an Incompressible Simple Fluid . 17 8. Static Behavior of Simple Fluids . . . . . . . . 19 III. General Theory of Viscometric Flows 9. The Kinematics of Simple Shearing Flow 21 10. The Viscometric Functions . . . . . . . . . . 22 11. The Dynamics of Simple Shearing Flow; Viscosity 26 12. The Definition of a Viscometric Flow 29 13. Curvilineal Flows. . . . . . . . 30 1. Kinematical Description . . . .